Method of welding thermoplastic film

ABSTRACT

A method of welding at least two layers of a thermoplastic film which comprises a copolymer or copolymer-polymer mixture selected from the group consisting of ethylenevinylacetate (EVA) copolymer, an EVA copolymer and polyethylene, an EVA copolymer and polypropylene, and an EVA copolymer and polyethylene and polypropylene, with the proviso that the concentration of vinylacetate in said film is from about 12 to about 28% by weight, said method comprising the steps of: 
     pressing said at least two layers of said thermoplastic film; 
     applying a high frequency current to said pressed layers in order to weld said layers together; and 
     recovering said welded layers.

This is a continuation of application Ser. No. 07/811,113, filed on Dec.20, 1991, now abandoned, which was abandoned upon the filing hereofwhich is a continuation-in-part of Ser. No. 07/673,390, filed Mar. 22,1991, now abandoned.

FIELD OF THE INVENTION

The present invention is directed to a method of welding, by highfrequency or ultrasonic vibrations, an environmentally friendlythermoplastic material, said material being particularly suitable as areplacement for high frequency welding of polyvinyl chloride containingmaterials.

BACKGROUND OF THE INVENTION

In the past decade, the concern of governments for ecology andenvironment has become one of the top, if not the top priority. In theUnited States, 80% of all trash is being landfilled, the remaining 20%being split between incineration and recycling. However, landfilling hasits limits, and soon, incineration and recycling will become the best,if not the only way of disposing of trash.

Governments throughout the world have enacted legislation concerning theuse and disposal of wastes, and it is likely that upcoming environmentallaws will be more strict and rigid against any kind of pollution.

Accordingly, the great challenge of industries in almost every field isto keep on producing goods at reasonable costs, while meetingenvironmental criteria more strict and the plastic industry is noexception.

At present, many items manufactured from plastic materials are generallymade of polyvinyl chloride (PVC). PVC is a versatile material, but hasserious environmental drawbacks. Incineration of PVC produceschlorinated dibenzofurans, chlorinated dibenzodioxins, and hydrochloricacid gas. It is now of common knowledge that dioxins and furans havebeen linked to diseases such as immuno-system failure, cancer, and birthdefects. Also, hydrochloric acid is a powerful corrosive substance, andwhen combined with atmospheric moisture, it significantly contributes toacid rain.

Since PVC materials also contain to, tic additives such as heavy metalsused as stabilizers and plasticizers, disposal of these coverings bylandfilling is highly undesirable because these additives are slowlyleached by water, and thus dispersed in the soil. Most of thesestabilizers are considered carcinogenic.

The use of these stabilizers has also led to bans on PVC incineration,and has raised questions concerning the acceptance of productscontaining PVC that could eventually end up in waste.

Many governments have already banned either production and/orimportation of PVC materials in their countries and this has lead to arace between manufacturers to find a non-toxic substitute for PVC whichcan be welded at high frequency. This represents a tremendous task.Plastic manufacturers are investing important amounts of money at everylevel to develop a new thermoplastic material suitable for highfrequency welding which would overcome all the serious drawbacks of PVC.In this research, many requirements must be met.

The new thermoplastic material must be produced competitively whilemeeting the desirable performance requirements. The process leading tothe final product should be susceptible to efficient continuousproduction operations. The thermoplastic material should also be strongenough to withstand stretching without the creation of holes, tears, ornon-uniform zones of stretching.

The processing of PVC or similar materials into sheets involvesextremely expensive machinery and the challenge is to develop athermoplastic material which can, on one hand, be processed into sheetswith existing machinery, and on the other hand, be converted intoconsumer goods by using the currently available machinery, especiallysuch machines which use high frequency welding methods. Generally, thePVC materials are welded by high frequency, and the replacingthermoplastic material must also be capable of being welded by highfrequency in any subsequent operation, and that represents the key stepleading to the final consumer good.

Finally, the thermoplastic material should be easily recyclable, or inthe alternative, should cause little damage to the environment whenincinerated. The present invention fulfills all the above requirements.

SUMMARY OF THE INVENTION

In accordance with the present invention, there is provided a method ofwelding at least two layers of a thermoplastic film which comprises acopolymer or copolymer-polymer mixture selected from the groupconsisting of ethylenevinylacetate (EVA) copolymer, an EVA copolymer andpolyethylene, an EVA copolymer and polypropylene, and an EVA copolymerand polyethylene and polypropylene, with the proviso that theconcentration of vinylacetate in said film is from about 12 to about 28%by weight, said method comprising the steps of:

pressing said at least two layers of said thermoplastic film;

applying a high frequency current to said pressed layers in order toweld said layers together; and

recovering said welded layers.

For convenience purposes, the above described film will be referred toas EVA film throughout the specification.

In an aspect of the invention, the EVA film comprises anethylenevinylacetate copolymer (EVA) and a polymer selected from thegroup consisting of polyethylene (PE), polypropylene (PP) and mixturesthereof, with the proviso that the concentration of vinylacetate in thefilm is from about 12 to about 28% by weight.

Preferably, the amount of vinylacetate in the EVA film is from about 14%by weight to about 2.5% by weight and more preferably, about 19% byweight.

In another aspect of the present invention, the layers of thethermoplastic film described above can be welded by ultrasonicvibrations.

The EVA film used in the method of the present invention may alsocontain one or more additives such as a color concentrate, a slip, afiller, an anti-block agent and the like

DETAILED DESCRIPTION OF THE INVENTION

In accordance with the present invention, there is provided a method ofwelding at least two layers of a thermoplastic film which comprises acopolymer or copolymer-polymer mixture selected from the groupconsisting of ethylenevinylacetate (EVA) copolymer, an EVA copolymer andpolyethylene, an EVA copolymer and polypropylene, and an EVA copolymerand polyethylene and polypropylene, with the proviso that theconcentration of vinylacetate in said film is from about 12 to about 28%by weight, said method comprising the steps of:

pressing said at least two layers of said thermoplastic film;

applying a high frequency current to said pressed layers in order toweld said layers together; and

recovering said welded layers.

The term "polyethylene" is meant to include high density polyethylene(HDPE), low density polyethylene (LDPE) and linear low densitypolyethylene (LLDPE) and the like, with the LLDPE being preferred.

The term "polypropylene" is meant to include polypropylene homopolymer,polypropylene copolymer, polypropylene terpolymer and the like, with thepolypropylene terpolymer being preferred.

The expression "high frequency welding" is synonymous of radio frequencywelding, and the meaning of these expressions is well known in this art.The frequency used in the high frequency welding, or radiofrequencywelding is of about 27 MHz.

All the polymers or copolymers used in the method of the invention arecommercially available on the market. As an example of such polymersthat may be mentioned: linear low density polyethylene polymer #11D1,manufactured and sold by DuPont Canada; ethylenevinylacetate copolymer#2803M, manufactured and sold by At Plastics; polypropylene homopolymerJY 6100, manufactured and sold by Shell Canada; polypropylene copolymerXSV 622, manufactured and sold by Himont; polypropylene terpolymerRA061, manufactured and sold by Himont; low density polyethylene,manufactured and sold by Nova Corporation under the trade mark NOVAPOL2FO219-A; and high density polyethylene HDPE 36156, manufactured andsold by Dow Chemical.

As an example of suitable EVA films that can be used in the method ofthe present invention, there may be mentioned those comprising fromabout 42 to 100% by weight of EVA copolymer having a vinylacetatecontent of 28% by weight, about 0 to 58% by weight of polyethylene, andfrom about 0 to 58% by weight of polypropylene. Preferably, the filmcomprises from about 42 to about 73% of EVA copolymer having avinylacetate content of about 28%, about 27 to about 58% ofpolyethylene, and/or about 27 to 58% of polypropylene.

It should be appreciated that an EVA copolymer having a vinylacetatecontent of about 12 to about 28% by weight can be used alone. However,because of the present high cost of EVA copolymer, it is preferable thatit be in admixture with other cheaper polymers such as polyethylene andpolypropylene, in order to produce consumer goods having a competitiveprice.

Currently, the processing of PVC material into a marketable item suchas, for example, a protective covering for ring binders or wallets forcarrying cheque books and other manufactured goods involves theextrusion of PVC into a film having the desired thickness. The PVC filmis then processed in a machine adapted to weld at least two layers ofsaid film around an object to be protected such as cardboard, or to weldat least two layers of said film for making other types of manufacturedgoods like garbage bags, food storage bags and the like, the layersbeing then welded by high frequency, which also preferably involves asimultaneous cutting step to discard unwanted material. Heat welding canalso be used instead of high frequency welding. However, from acommercial and industrial point of view, high frequency welding is muchfaster and efficient.

A conventional apparatus for carrying out the method of high frequencywelding of the present invention comprises at least a press and meansfor welding at high frequency. Many types of high frequency weldingapparatus are available on the market, such as COLPITT, KIEFEL, COSMOS,HISEN and the like. It should therefore be kept in mind that the methodof the present invention can be performed on any of the these machines.

In more details, the method of the present invention comprises applyingpressure onto at least two layers of an EVA film defined above by usinga press preferably equipped with a heatable plate. The temperature ofthe plate can vary from about room temperature to as high as possible,as long as the film does not start to melt, thus causing it to stick tothe plate. In other words, the highest possible temperature of the plateis the melting point of the composition of the film to be welded.Preferably the plate is heated around 70°-80° C. because it allows ashorter welding time, and requires less energy for welding.

The pressure applied is function of the thickness of the film, or thenumber of layers of said film. It is highly desirable to apply suchpressure in order to obtain effective welding. Usually, the operator ofthe high frequency welding apparatus is well aware of the optimalpressure to be applied.

Some, but not all, high frequency welding apparatus are equipped with apre-welding time option which permits an improved settlement of the filmto be welded, as well as the application of a more uniform pressure onthe film, prior to high frequency welding. Though not essential, suchpre-welding operation is recommended to obtain better results.

Subsequently, the layers are welded by high frequency at a frequency ofabout 27 MHz, which is the usual frequency provided in high frequencywelding apparatus. The welding time is also function of numerousparameters, such as the type of press (hydraulic, air etc . . . ), thethickness of the layers welded, the temperature of the plate etc. . . .Again, the operator of the high frequency apparatus is well aware ofthese requirements, and can determine the optimal conditions to maximizethe method resulting in a satisfactory weld.

The high frequency welding step is preferably followed by a coolingperiod in order to allow the newly welded layers to cool down, and theweld to strengthen before the press is removed.

Finally, the excess of material, if any, is stripped, providing thefinished goods.

The high frequency welding step described above can also be replaced byan ultrasonic vibration welding step. As an example of a suitableultrasonic vibrations welding apparatus, there may be mentioned the MachSonic type SWP-14A. Obviously, other conventional ultrasonic vibrationswelding apparatus may be used, such as King Ultrasonic Mach. etc. . . .

The user is usually equipped with the machine that serves his purposes,which can be other than welding the thermoplastic films disclosed in thepresent application. It should also be mentioned that the ultrasonicvibrations welding step is performed at room temperature.

In developing a thermoplastic substitute for PVC, two critical issueshad to be considered. First, the substitute must be non-toxic for theenvironment, with mechanical properties at least similar or superior tocurrent PVC coverings; and second, it is obviously imperative that thecovering material be weldable by high frequency in similar conditions.

The thermoplastic substitute film should also possess the followinghighly desirable characteristics:

the stripping: the conventional method for high frequency weldinginvolves the simultaneous "cutting" of the excess of material by acutting dye present in the same matrix. The excess of material is then"stripped" manually without tearing;

the rigidity: the film should have a good resistance to torsion andshearing;

cold crack: since the goods containing a protective covering may besubmitted to low temperatures, for example, a ring binder forgotten in acar in the winter time, the covering should possess properties such thatit will remain flexible even after being submitted to low temperatures.Furthermore, the weld should not be affected or altered;

fatigue: items such as ring binders containing a covering or wallets forcheque books, are opened and closed hundreds of times. It is thereforeessential that the covering material and the weld be resistant to crackscaused by fatigue.

The thermoplastic EVA film used in the method of the present inventioncomplies with all the above requirements, and in some instances, hasunexpectedly superior properties and advantages over PVC. Extrusion ofthe composition into a film is carried in a conventional manner withstandard equipment well known in this field of the art. The thickness ofthe resulting sheet or film can be adjusted at will, depending on itsintended use and the limits of the extruding machine. Typically, itvaries from about 0.008 to about 0.022 inches.

Many techniques other than extrusion are available to the skilledworkman for obtaining an EVA film suitable for the method of the presentinvention. However, the extrusion is preferred.

The chemical properties of the EVA film and its combustion productsresulting from incineration have been analyzed. Also, the mechanicalproperties of consumers' goods containing at least two layers of an EVAfilm welded in accordance with the method of the present invention, forexample, a ring binder, have been extensively evaluated.

Upon analysis, it has been found that the EVA layer or film used in themethod of the present invention is free of heavy metals such as Ba, Cd,Cr, Se and Hg, and also free of halogen atoms, whereas some PVC samplesshow up to 2450 ppm of Ba, 1240 ppm of Ba, and 480 ppm Cr. Furthermore,incineration of the EVA film leads to water and CO₂, which are obviouslynon-toxic products.

PVC materials contain phthalates used as plasticizers for enhancing thecold crack resistance of the covering. These chemicals are highly toxicfor humans and the environment, and their incineration may givedibenzodioxins and dibenzofurans, well known for their high level oftoxicity.

The cold crack temperature of PVC is about -20° C., whereas the coldcrack temperature of a protective ring binder covering prepared with theEVA film is lower than -55° C.

A fatigue test has been carried out in the following manner: a ringbinder protected with a covering consisting of two layers of the EVAfilm welded by high frequency with a cardboard inserted in between, wasplaced on an apparatus allowing opening and closing of said binder. Asimilar experiment was carried out with a PVC covered ring binder. After2500 cycles, the PVC binder was severely damaged, whereas the otherbinder covered with the EVA film remained intact after 80 000 (eightythousand) cycles.

The EVA film may also contain a color concentrate, such as, for example,blue concentrate #4PPP201 manufactured and sold by Resco Colors Ltd. Anyother suitable color concentrate can be used in said film, as long asthe high frequency welding properties are not impaired.

Other additives such as a slip used to lower the coefficient offriction, a filler used to enhance the rigidity of the film, ananti-block agent used to lower the interfacial blocking properties andthe like, can also be added in the film. An example of a slip isErucamide, manufactured and sold by Canada Colors. An example of afiller is talc manufactured and sold by Canada Colors. An example of ananti-block agent is silica, manufactured and sold by Canada Colors.

The concentration of each of these additives is determined by theintended use of the finished goods. It must be kept in mind, however,that the concentration should neither alter the weldability of the EVAfilm, nor the resistance of the weld between two or more layers of thefilm.

The following examples are provided to illustrate the present inventionrather than limit its scope.

EXAMPLE 1

The following products are blended together:

68% by weight of ethylenevinylacetate copolymer (EVA), #2803M,manufactured and sold by At Plastics, wherein the content ofvinylacetate is 28%;

28% by weight of LLDPE #11D1, manufactured and sold by DuPont Canada;and

4% by weight of color concentrate #4PPP201, manufactured and sold byResco Colors Ltd., having a polypropylene homopolymer content of about60% by weight.

This blend is melted, giving a composition containing 19% by weight ofvinylacetate. The melted composition is then extruded in a conventionalmanner with standard extruding equipment to produce a film having athickness of approximately 0.008 inches. Depending on the intended use,the thickness can be adjusted as desired.

EXAMPLE 2 High Frequency Welding

A cardboard is placed between two layers of the film prepared in Example1, and processed through a high frequency welding machine COLPITT SerialNumber 902216, under the following experimental conditions:

temperature of the plate: 75° C.

pressure applied: 40 bar

frequency: approximately 27 MHz

amplitude: 9.5

pre-welding time: 0.5 second

welding: 2.0 second

cooling time: 0.2 second

anode current: between about 1 to about 2 amperes

grid current: about 0.5 ampere

to lead to the desired binder after the mounting of suitable rings.

The amplitude is the last parameter adjusted on the high frequencywelding apparatus. This feature is not present in every apparatus, butwhen it is, it allows a better free tuning.

It is to be noted that the anode current and the grid current indicatewhether the tuning of the apparatus is adequate. In other words, onceall the other parameters are adjusted, the anode current should bebetween 1 and 2 amperes, and the grid current should be around 0.5 inorder to obtain satisfactory high frequency welding of the EVA film.

EXAMPLE 3

Proceeding in the same manner as in Example 1, the followingcompositions were prepared and extruded to provide a film. The valueslisted in the table are in % by weight. For films 4 to 44, the EVA usedhad a vinylacetate content of 28% by weight.

    __________________________________________________________________________    FILM                                                                          #   EVA LLDPE                                                                             LDPE                                                                              HDPE                                                                              PP1 PP2 PP3 PP4 % VA                                      __________________________________________________________________________    1   100                             10                                        2   100                             28                                        3   100                             40                                        4   42.86                                                                             53.14                   4   12                                        5   42.86   53.14               4   12                                        6   42.86       53.14           4   12                                        7   42.86           53.14       4   12                                        8   42.86               53.14   4   12                                        9   42.86                   53.14                                                                             4   12                                        10  50  46                      4   14                                        11  50      46                  4   14                                        12  50          46              4   14                                        13  50              46          4   14                                        14  50                  46      4   14                                        15  50                      46  4   14                                        16  57  39                      4   16                                        17  57      39                  4   16                                        18  57          39              4   16                                        19  57              39          4   16                                        20  57                  39      4   16                                        21  57                      39  4   16                                        22  64  32                      4   18                                        23  64      32                  4   18                                        24  64          32              4   18                                        25  64              32          4   18                                        26  64                  32      4   18                                        27  64                      32  4   18                                        28  68      28                  4   19                                        29  68          28              4   19                                        30  68              28          4   19                                        31  68                  28      4   19                                        32  68                      28  4   19                                        33  713 24.5                    4   20                                        34  71.5    24.5                4   20                                        35  71.5        24.5            4   20                                        36  71.5            24.5        4   20                                        37  71.5                24.5    4   20                                        38  71.5                    24.5                                                                              4   20                                        39  72.7                                                                              23.3                    4   22                                        40  72.7    23.3                4   22                                        41  72.7        23.3            4   22                                        42  72.7            23.3        4   22                                        43  72.7                23.3    4   22                                        44  72.7                    23.3                                                                              4   22                                        __________________________________________________________________________     note:                                                                         PP1 = polypropylene homopolymer                                               PP2 = polypropylene copolymer                                                 PP3 = polyproplene terpolymer                                                 PP4 = color concentrate                                                       % VA = % of vinylacetate in the film.                                    

EXAMPLE 4

Proceeding in the same manner as in Example 1, a film having thefollowing composition was prepared:

68% by weight of ethylenevinylacetate copolymer (EVA), #2803M,manufactured and sold by At Plastics, wherein the content ofvinylacetate is 28%;

4% by weight of color concentrate #4PPP201, manufactured and sold byResco Colors Ltd., having a polypropylene homopolymer content of about60% by weight;

2.5% of slip master batch which is a 5% by weight dispersion oferucamide in an appropriate carrier; and

25.5% of a mixture comprising 40% by weight of talc and 60% by weight ofLLDPE.

This film provided excellent results under high frequency welding andultrasonic vibrations welding in accordance with the present invention.

EXAMPLE 5

Two layers of films 28 to 31 as listed in Example 3, each layer having athickness of about 0.013 inch, are processed through an ultrasonicvibrations welding machine Mach Sonic type SWP-14A at a 15 KHz frequencyunder the following conditions:

    ______________________________________                                              Welding  Power    Welding      P.sub.1                                                                             P.sub.2                                  delay    delay    time   Hold  (kg/  (kg/                               Film  (sec.)   (sec.)   (sec.) (sec.)                                                                              cm.sup.2)                                                                           cm.sup.2)                          ______________________________________                                        28    0.3      0.35     0.25   0.5   2     5                                  29    0.3      0.35     0.30   0.5   2     5                                  30    0.3      0.35     0.35   0.5   2     5                                  31    0.3      0.35     0.40   0.5   2     5                                  ______________________________________                                         P.sub.1 corresponds to the pressure applied initially by the horn on the      layers at time = 0, and P.sub.2 is the pressure applied during the            welding.                                                                 

ANALYSIS OF THE FILMS

Each film obtained in Example 3 was submitted to evaluation of severalmechanical properties that are:

easiness of welding by high frequency and ultrasonic vibrations

stripping

rigidity

cold crack

weld resistance

fatigue resistance

It is to be understood that the films were tested especially forprotective covering purposes of consumer goods, and therefore, evaluatedas such. Accordingly, the criteria of evaluation might be differentdepending on the intended use, for example, a food storage bag or agarbage bag.

In order to determine a range of accessibility, films #1 and 3 consistedin an EVA copolymer alone with a concentration of vinylacetate of 10 and40% by weight respectively.

The film #1 cannot be welded by high frequency or ultrasonic vibrations,and therefore, no further evaluation of this film was carried out.

The composition of film #3 cannot be extruded at all. Accordingly, thefirst results indicated that the concentration of vinylacetate in thefilm must be higher than 10% and lower than 40% by weight.

The film #2 gave excellent results in all the tests, except for therigidity, which was rather poor for the intended use, that is protectivecovering.

In a general manner, films 2 and 4 to 44 possess significantly higherfatigue resistance over similar PVC sheets, as well as a much lower coldcrack temperature.

The rigidity of the film slightly decreases with the increase of theconcentration of vinylacetate in the film. On the other hand, theeasiness of welding, either by high frequency or ultrasonic vibrations,the stripping and the weld resistance increase significantly with theincrease of concentration of vinylacetate.

Considering all the de-sired characteristics, films 27 to 34 and thefilm of Example 1, wherein the concentration of vinylacetate in the filmis from 18 to 20%, have given the more preferred film for performing themethod of the present invention.

We claim:
 1. A method of high frequency welding together layers of athermoplastic film comprising vinylacetate in a concentration of about12 to 28% by weight of said thermoplastic film and a . .copolymer or.!.copolymer-polymer mixture selected from the group consisting of:. .anethylenevinylacetate EVA copolymer,.!. an .Iadd.ethylenevinylacetate.Iaddend.EVA copolymer and polypropylene, an EVA copolymer andpolyethylene, and an EVA copolymer and polypropylene and polyethylene,the method comprising the steps of: a) pressing together layers of saidthermoplastic film between solid surfaces; b) applying a high frequencyelectromagnetic wave energy to said pressed layers so as to effect highfrequency welding together of said layers, said film being capable ofbeing welded by high frequency wave-energy without requiring theapplication of heat to said layers of said film prior to high frequencywelding said layers; and c) releasing said pressure on said layers,cooling said layers and recovering said welded layers.
 2. The method ofclaim 1 wherein the concentration of vinylacetate in said thermoplasticfilm is from 14 to 25% by weight of said thermoplastic film.
 3. Themethod of claim 1 wherein the concentration of vinylacetate in saidthermoplastic film is about 19% by weight of said thermoplastic film. 4.The method of claim 1 wherein said thermoplastic filmcomprises:.Iadd.(a) .Iaddend.42 to . .100%.!. .Iadd.73% .Iaddend.byweight of an EVA copolymer comprising about 28% by weight ofvinylacetate .Iadd.and .Iaddend. . .0 to 58% by weight of polyethylene,and optionally 0 to 58% by weight of polypropylene.!. .Iadd.(b) up to58% by weight of polyethylene or polypropylene.Iaddend..
 5. The methodof claim 1 wherein said thermoplastic film comprises:42 to 73% by weightof an EVA copolymer comprising about 28% by weight of vinylacetate, 27to 58% by weight of polyethylene, and optionally 27 to 58% by weight ofpolypropylene.
 6. The method of claim 1 wherein said method comprisingthe additional step of warming said solid surfaces in order toaccelerate the time required for high frequency welding of said layers.7. The method of claim 5 wherein said thermoplastic film comprises oneor more additives selected from the group consisting of a slip agent, ananti-block agent, and a filler.
 8. The method of claim 5 wherein saidthermoplastic film has a thickness of about 0.008 to 0.022 inches. 9.The method claim 5 wherein said high frequency wave energy is applied ata frequency of about 27 MHz.